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Chemistry  /  Chem 2133  ·  Procedure · 60–90 seconds

Calculating K from ΔG°

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Calculating an equilibrium constant from a standard free energy change means substituting ΔG°, converted to joules, and the absolute temperature into ΔG° = −RT ln K, isolating ln K, and solving for K by exponentiating both sides.

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For a reaction with ΔG° = −29.0 kJ/mol at 298 K, first converted to −29,000 J/mol, ln K = −ΔG°/RT = 29,000/(8.314 × 298) ≈ 11.7, so K = e¹¹·⁷ ≈ 1.2 × 10⁵, a large constant consistent with the strongly negative ΔG° and, by Chem 2130, an equilibrium mixture favoring products heavily.

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Leaving ΔG° in kilojoules while R is expressed in joules per mole-kelvin mismatches units in exactly the way Chem 2115 already warns against, scaling ln K by a factor of a thousand.