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Chemistry  /  Chem 0697  ·  Procedure · 60–90 seconds

Calculating Heat Released by Combustion of a Given Mass

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Calculating the heat released by burning a given mass of fuel means converting that mass to moles using the fuel's molar mass, then multiplying by its standard enthalpy of combustion, which is defined on a per-mole basis rather than per gram.

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One liter of isooctane, at a density of 0.692 g/mL, has a mass near 692 g. Dividing 692 g by isooctane's molar mass, about 114.23 g/mol, gives roughly 6.06 mol of isooctane in that liter. Multiplying 6.06 mol by isooctane's standard enthalpy of combustion, about −5460 kJ per mole, gives approximately −3.3 × 10⁴ kJ released by burning the full liter, an amount large enough to melt roughly 99 kg of ice.

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Multiplying the fuel's mass in grams directly by its per-mole enthalpy of combustion, skipping the conversion to moles entirely, produces an answer wrong by the fuel's molar mass.

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